Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism

Answers

Answer 1

Answer:

See explanation and image attached

Explanation:

According to Markovnikov regiochemistry, the negative part of the addendum is joined to the more substituted carbon atom. The addition of H-OH to alkynes occurs in the presence of mercury(II) sulfate as a Lewis acid catalyst.

So, the -OH group is added to the highly substituted carbon and the H adds to the less highly substituted carbon.

The enol produced is shown in the mechanism attached to this answer. Rearrangement of this enol form due to keto-enol tautomerism yields the ketone as shown.

Image credit: chemistry steps

Alkynes Do Not React Directly With Aqueous Acid As Do Alkenes, But Will Do So In The Presence Of Mercury(II)

Related Questions

A sample of titrations of 0.200 M sodium hydroxide (NaOH) being added to 30.0 mL of hydrochloric acid (HCl) of unknown concentration. Measure the volume of sodium hydroxide needed to neutralize the HCl, and calculate the concentration of the HCl.

Answers

Answer:

Assuming 20.0 mL of 0.2 M NaOH is used to neutralize 30 mL of the HCl of unknown concentration, the concentration of the hydrochloric acid is 0.133 M.

Note: The volume of NaOH used isnot given and issp to be determined by titration.

Explanation:

The question is a lab activity. Therefore, the volume of 0.2 M NaOH required for the neutralization of 30.0 mL of hydrochloric acid of unknown concentration is to be determined from titration. However, assuming a certain volume of the base is used for the complete neutralization of the acid, the concentration of the acid can be calculated.

Assuming 20.0 mL of 0.2 M NaOH is used to neutralize 30 mL of the HCl of unknown concentration, the concentration of the hydrochloric acid can be calculated thus:

Step 1: Balanced chemical equation of reaction:

HCl + NaOH ---> NaCl + H₂O

From the equation of the reaction, 1 mole of NaOH reacts with 1 mole of HCl to produce 1 mole of NaCl and water.

Step 2: Determine the number of moles of NaOH in 20.0 mL of 0.200 M solution

Molarity = number of moles/volume in Litres

Number of moles = molarity × volume in litres

Volume of NaOH in litres = 20 ml × 1 litre/1000ml = 0.02 litres

Number of moles NaOH = 0.02 L × 0.2 M = 0.004 moles

Therefore, 0.00 M of NaOH reacted with 0.004 moles of HCl

Step 3: Determine concentration of HCl

Molarity or concentration = number of moles / volume in litres

Number of moles of HCl = 0.004 moles

Volume of HCl in litres = 30.0 mL × 1 L/1000 mL = 0.03 L

Concentration of HCl = 0.004 moles / 0.03 L = 0.133 M

Therefore, assuming 20.0 mL of 0.2 M NaOH is used to neutralize 30 mL of the HCl of unknown concentration, the concentration of the hydrochloric acid is 0.133 M.

A sample of oxygen gas occupies a volume of 2.,0cm3 at pressure of 700K pa. what will be pressure of the same sample occupies a volume of 150cm, assume temperature remains constant​

Answers

Answer:

The pressure will be 933.33 Kpa

Explanation:

Given that:

Volume V₁ = 200 cm³  (note, there is a mistake in the volume. It is supposed to be 200 cm³)

Pressure P₁ = 700 Kpa

Pressure P₂ = ??? (unknown)

Volume V₂ = 150 cm³

Temperature = constant

Using Boyle's law:

PV = constant

i.e.

P₁V₁ = P₂V₂

700 Kpa × 200 cm³ = P₂ × 150 cm³

P₂ = (700 Kpa × 200 cm³)/150 cm³

P₂ = 933.33 Kpa

What causes an ice cube to melt when removed from a freezer?

Answers

Answer:

the melting process begins right away because the air temperature around the ice cubes is warmer than the temperature in the freezer

The temperature in the room is higher than the temperature in the freezer, thus causing the melting state of the ice cube when it is removed from the freezer.

I NEED THIS NOW NO LINKS OR ILL REPORT PLZZZ
What is an example of a chemical property?
Odensity

O reactivity

Omalleability

O solubility

Answers

#2 reactivity is the answer

Part C
Read about an improved version of an atmospheric water generator e, and write a
one-paragraph description of this technology.

Answers

Answer:

Atmospheric water generator is used in regions that have scarcity of water or have polluted water. These generators are reliable sources of clean and safe water and hence reduces dependency on bottled water.

Atmospheric water generator extract water from the air (humid air) through condensation. Extracted water then cools down to temperature below its dew point  thereby producing potable drinking water.

Explanation:

Atmospheric water generator is used in regions that have scarcity of water or have polluted water. These generators are reliable sources of clean and safe water and hence reduces dependency on bottled water.

Atmospheric water generator extract water from the air (humid air) through condensation. Extracted water then cools down to temperature below its dew point  thereby producing potable drinking water.

Answer:

A device that collects water from humid ambient air is known as an atmospheric water generator. Condensation is the process of extracting water vapor from the air by chilling it below its dew point, exposing it to desiccants, or pressurizing it. An AWG, unlike a dehumidifier, is meant to make the water drinkable. Because there is nearly always a little amount of water in the air that may be collected, AWGs are useful in situations where clean drinking water is difficult or impossible to get. Cooling and desiccants are the two most common ways used.

Explanation:

Calculate the molality of each of the following solutions:
(a) 14.3 g of sucrose (C12H22O11) in 685 g of water,
(b) 7.15 moles of ethylene glycol (C2H6O2) in 3505 g of water.

Answers

Answer:

(a) The molality of this solution is 0.0613[tex]\frac{moles}{kg}[/tex]

(b)The molality of this solution is 2.04[tex]\frac{moles}{kg}[/tex]

Explanation:

The molality (m) of a solution is defined as the number of moles of solute present per kg of solvent.

The Molality of a solution is determined by the expression:

[tex]Molality=\frac{number of moles of solute}{kilograms of solvent}[/tex]

Molality is expressed in units [tex]\frac{moles}{kg}[/tex]

(a) You have 14.3 g of sucrose (C₁₂H₂₂O₁₁), the solute. With the molar mass of sucrose being 342 [tex]\frac{g}{mole}[/tex], then 14.3 grams of the compound represents the following number of moles:

[tex]14.3 grams*\frac{1 mole}{342 grams} =[/tex] 0.042 moles

Having 685 g= 0.685 kg (being 1000 g= 1 kg) of water, the solvent, molality can be calculated as:

[tex]molality=\frac{0.042 moles}{0.685 kg}[/tex]

Solving:

molality= 0.0613[tex]\frac{moles}{kg}[/tex]

The molality of this solution is 0.0613[tex]\frac{moles}{kg}[/tex]

(b) In this case you have 7.15 moles of ethylene glycol (C₂H₆O₂), the solute, in 3505 g (equal to 3.505 kg) of water, the solvent, molality can be calculated as:

[tex]molality=\frac{7.15 moles}{3.505 kg}[/tex]

Solving:

molality= 2.04[tex]\frac{moles}{kg}[/tex]

The molality of this solution is 2.04[tex]\frac{moles}{kg}[/tex]

How many moles are in 3.5 x 10^24 molecules of methane gas?

Please show work, will give brainliest

Answers

Answer:

5.81 moles

Explanation:

To find the number of moles (n) in 3.5 x 10²⁴ molecules of methane gas, we divide the number of molecules by Avagadro's number (nA). That is,

n = number of molecules ÷ 6.02 × 10²³

According to this question, 3.5 x 10^24 molecules of methane gas was given, hence,

n = 3.5 × 10²⁴ ÷ 6.02 × 10²³

n = 3.5/6.02 × 10(24 - 23)

n = 0.5814 × 10¹

n = 5.81 moles

I think I put my in it when I asked Jane about her ex-husband
root

Answers

What does this mean?

You combine 0.75 moles formate and 0.85 moles formic acid to make a buffer solution. The Ka of formic acid is 1.8x10-4 what is the pH of the solution

Answers

Answer:

pH = 3.68

Explanation:

We can solve this problem by using Henderson-Hasselbach's equation:

pH = pKa + log[tex]\frac{[Formate]}{[Formic Acid]}[/tex]Where pKa = -log(Ka)pKa = -log(1.8x10⁻⁴) = 3.74

Assuming we have 1 L of the buffer solution then the molar concentrations of formate and formic acid would be:

[Formate] = 0.75 mol / 1 L = 0.75 M[Formic Acid] = 0.85 mol / 1 L = 0.85 M

We now have all required data to calculate the pH:

pH = 3.74 + log[tex]\frac{0.75}{0.85}[/tex]pH = 3.68

Ibuprofen, a well‑known, non‑steroidal anti‑inflammatory drug, has chirality.

a. True
b. False

Answers

Answer:

A (True)

Explanation:

Because ibuprofen has a chiral carbon center (carbon bonded to 4 distinct groups of atoms).

This means that a mixture of ibuprofen can rotate plane-polarized light equally in both the clockwise and counterclockwise direction.

Answer:true

Explanation: ibuprofen is commonly used for most pain, aches ect

What are the semi structural formula of C6h14 Isomers?

Answers

Answer:

n-hexane

2-methylpentane

3-methylpentane

2,2-dimethylbutane

2,3-dimethylbutane

Explanation:

There are 5 structural isomers of C6H14.

n-hexane

2-methylpentane

3-methylpentane

2,2-dimethylbutane

2,3-dimethylbutane

Chrysanthenone is an unsaturated ketone. If Chrysanthenone has M+ = 150 and contains 2 double bond(s) and 2 ring(s); what is its molecular formula? Enter the formula in the form CH first, then all other atoms in alphabetical order; do not use subscripts. The formula is case-sensitive.

Answers

Answer:

the Molecular formula will be; C10H14O

Explanation:

Given the data in the question;

Chrysanthenone is an unsaturated ketone,

it has M+ = 150 and contains 2 double bond(s) and 2 ring(s).

molecular formula = ?

we know that ketone contain 1 oxygen and mass of oxygen is 16

so mass of the C and H remaining will be;

⇒ 150 - 16 = 134

Now we determine the number of C atoms;

⇒ 134 / 13 = 10

hydrocarbon with 10 hydrogen atom have CnH2n+2 means

⇒ ( 10 × 2 ) +2 = 22 hydrogens

But then we have 3 unsaturation meaning 6 hydrogens less and also we have ring meaning 2 more hydrogens

⇒ 22 - 6 - 2 = 14

Hence the Molecular formula will be; C10H14O

How many grams of KCl solid do I need to make 500 ml of 8% KCl solution

Answers

Answer:

40 grams of KCI are required to make 500 ml of 8% solution.

For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid), the equilibrium constant expression is: _________

a. K = [ H+] [NO2-] / [HNO2]
b. K = [ H+] [N] [O]2 / [HNO2]
c. K = [ H+] [NO2-] / [HNO2]
d. K = [H+]2 [NO2-] / [HNO2]
e. None of these

Answers

Answer: For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid), the equilibrium constant expression is K = [ H+] [NO2-] / [HNO2].

Explanation:

An expression that depicts the ratio of products and reactants raised to the power of their coefficients at equilibrium is called equilibrium constant.

An equilibrium constant is denoted by the symbol 'K'.

For example, the dissociation of nitrous acid in aqueous solution is as follows.

[tex]HNO_{2} \rightleftharpoons H^{+} + NO^{-}_{2}[/tex]

Hence, its expression for equilibrium constant is as follows.

[tex]K = \frac{[H^{+}][NO^{-}_{2}]}{[HNO_{2}]}[/tex]

Thus, we can conclude that for the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid), the equilibrium constant expression is K = [ H+] [NO2-] / [HNO2].

Which is an example of poor safety practices when working outdoors

Answers

Answer:

C

Explanation:

u can't touch a chemical with bare skin

Answer:

touching a chemical with his or her bare skin.

Guys! I need a long inforation about...

"Colloidal solutions
Types of colloids
Formation of colloids"

Please! And thank you ​

Answers

A colloid is a mixture in which one substance of microscopically dispersed insoluble particles are suspended throughout another substance. However, some definitions specify that the particles must be dispersed in a liquid, and others extend the definition to include substances like aerosols and gels.

The types of colloids includes sol, emulsion, foam, and aerosol.

Sol is a colloidal suspension with solid particles in a liquid.

Emulsion is between two liquids.

Foam is formed when many gas particles are trapped in a liquid or solid.

Aerosol contains small particles of liquid or solid dispersed in a gas.

Explanation:

everything can be found in the picture

Can someone help me with this one

Answers

Answer:

Easy my dude let me help you out

A.In

B.27

C.73

D.49

E.56

F.56

G.114

H.180

Also with protons and electrons they equal the same atomic number

Nitric acid (HNO3) reacts with ammonia (NH3) in aqueous solution. Use your knowledge of nitric acid to decide what type of reaction arrow(s) to use. $$ Part 2 (1 point) Sulfuric acid (H2SO4) reacts with ammonia in aqueous solution. Use your knowledge of sulfuric acid to decide what type of reaction arrow(s) to use. $$

Answers

Answer:

Both reactions are acid-base reactions

Explanation:

An acid base reaction is a reaction that occurs between an acid and a base. This reaction often leads to the formation of a salt in the process. The nature of the salt depends on the type of acid and base that reacted in the process.

Both HNO3 and H2SO4 are strong acids. However, ammonia is a weak base. The acid base reaction between ammonia and these strong acids is shown below;

HNO3(aq) + NH3(aq) ------>NH4NO3(aq)

H2SO4(aq) + 2NH3(aq) ----> (NH4)2SO4(aq)

anuvia, the trade name for sitagliptin, was introduced in 2006 for the treatment of type 2 diabetes. In what type of orbital does the lone pair on each N atom reside.

Answers

Answer: hello your question is poorly written below is the complete question

answer:

For N1 :  sp³  orbital

For N2:  p orbital

For N3 : p orbital

For N4 : sp² orbital

For N5 : sp² orbital

Explanation:

Determining the type of orbital in which the lone pair on each N atom will reside.

From the configuration attached below we can determine the type of orbital and they are ;

For N1 :  sp³  orbital

For N2:  p orbital

For N3 : p orbital

For N4 : sp² orbital

For N5 : sp² orbital

PLS HELP The average atomic mass of carbon is 12.01 amu. Based on the atomic
masses of the two isotopes of carbon, how do the relative abundances of the
isotopes compare?

Answers

Answer:

B. There is a very large percentage of C-12.

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to realize that, since the average atomic mass is 12.01 amu, then the C-12, with an atomic mass of 12.000 am prevails over C-13 with an atomic mass of 13.003 amu as long as the average is nearer to the former.

In such a way, the answer will be B. There is a very large percentage of C-12.

Regards!

an alkane group has a formula of CxH6, determine the value of x​

Answers

Answer:

[tex]x = 2[/tex]

Explanation:

General formula for alkanes

[tex]C _{n}H _{2n + 2}[/tex]

since H = 6

[tex]2n + 2 = 6 \\ 2n = 4 \\ n = 2 \\ since \: x = n\\ \therefore \: x = 2[/tex]

Answer:

x=2

Explanation:

Because alkanes have a general formula of CnH(2n+2).

We known that 2n+2=6, so we solve for n.

2n+2=6

2n=4

n=2

Thus, there are 2 carbon atoms.

Gold is a precious metal that is chemically unreactive. It is used mainly in jewelry, dentistry, and electronic devices. A piece of gold ingot with a mass of 301 g has a volume of 15.6 cm3. Calculate the density of gold.

Answers

Answer:

Density = 19.3 g/cm³

Explanation:

In order to answer this question we need to keep in mind the following definition of density:

Density = Mass / Volume

As both the mass and the volume are given by the problem, we can proceed to calculate the density of gold:

Density = 301 g / 15.6 cm³Density = 19.3 g/cm³

a. Giải thích vì sao tính bazơ tăng từ LiOH đến CsOH?

Answers

i cant understand what you’re saying

The information below describes a redox reaction.
Ag+ (aq) + Al(s) — Ag(s) + Al3+ (aq)
Ag+ (aq) + -> Ag(s)
Al(s)->A3+ (aq) + 3e-
What is the coefficient of silver in the final, balanced equation for this reaction?

Answers

Answer:

Al°(s)  + 3Ag⁺(aq) => Al⁺³(aq) + 3Ag(s)

Explanation:

Oxidation:                            Al°(s) =>   Al⁺³(aq) + 3e⁻

Reduction:           3Ag⁺(aq) + 3e⁻ => 3Ag°(s)

_________________________________________

Net Rxn:           Al°(s)  + 3Ag⁺(aq) => Al⁺³(aq) + 3Ag(s)

One mole of neutral aluminum atoms (Al°(s)) undergo oxidation delivering 3 moles  of electrons to 3 moles silver ions (3Ag⁺³(aq)) that are reduced to 3 moles of neutral silver atoms (3Ag°(s)) in basic standard state 25°C; 1atm.

A balanced equation obeys the law of conservation of mass. According to the law of conservation of mass, mass can neither be created nor be destroyed. The coefficient of silver is 3.

What is a balanced equation?

A balanced chemical equation can be defined as the chemical equation in which the number of reactants and products on both sides of the equation are equal. The amount of reactants and products on both sides of the equation will be equal in a balanced chemical equation.

The numbers which are used to balance the chemical equation are called the coefficients. The coefficients are the numbers which are added in front of the formula.

The balanced chemical equation for the given redox reaction is given as:

Al (s) + 3 Ag⁺ (aq)  → Al³⁺ (aq) + 3Ag (s)

Thus the coefficient of silver is 3.

To know more about balanced equation, visit;

https://brainly.com/question/29769009

#SPJ7

g Select the statement that best answers the following question What effect does the cation of an ionic compound have on the appearance of the solution? The cation affects the intensity of the color more than the color of the solution. The cation affects the color of the solution more than the intensity of the color. The cation does not affect the color or color intensity of the solution. The cation only affects the intensity of the color in a solution.

Answers

Answer:

The cation affects the intensity of the color more than the color of the solution.

Explanation:

According to Beer Lambert law, the intensity of the colour of the solution depends on the concentration of the specie responsible for the colour in the solution.

Let us recall that transition metal compounds are coloured in solution due to electronic transitions.

Therefore, the cation affects the intensity of the color more than the color of the solution.

what's the ph of 0.0000067 m hcl solution

Answers

Answer:

[tex]pH = - log[H {}^{ + } ] \\ = - log(0.0000067) \\ pH = 5.17[/tex]

A) The average molecular speed in a sample of Ar gas at a certain temperature is 391 m/s. The average molecular speed in a sample of Ne gas is ______ m/s at the same temperature.
B) The rate of effusion of Xe gas through a porous barrier is observed to be 7.03×10-4 mol / h. Under the same conditions, the rate of effusion of SO2 gas would be ______ mol / h

Answers

Answer:

For A: The average molecular speed of Ne gas is 553 m/s at the same temperature.

For B: The rate of effusion of [tex]SO_2[/tex] gas is [tex]1.006\times 10^{-3}mol/hr[/tex]

Explanation:

For A:

The average molecular speed of the gas is calculated by using the formula:

[tex]V_{gas}=\sqrt{\frac{8RT}{\pi M}}[/tex]

     OR

[tex]V_{gas}\propto \sqrt{\frac{1}{M}}[/tex]

where, M is the molar mass of gas

Forming an equation for the two gases:

[tex]\frac{V_{Ar}}{V_{Ne}}=\sqrt{\frac{M_{Ne}}{M_{Ar}}}[/tex]          .....(1)

Given values:

[tex]V_{Ar}=391m/s\\M_{Ar}=40g/mol\\M_{Ne}=20g/mol[/tex]

Plugging values in equation 1:

[tex]\frac{391m/s}{V_{Ne}}=\sqrt{\frac{20}{40}}\\\\V_{Ne}=391\times \sqrt{2}=553m/s[/tex]

Hence, the average molecular speed of Ne gas is 553 m/s at the same temperature.

For B:

Graham's law states that the rate of diffusion of a gas is inversely proportional to the square root of the molar mass of the gas. The equation for this follows:

[tex]Rate\propto \frac{1}{\sqrt{M}}[/tex]

Where, M is the molar mass of the gas

Forming an equation for the two gases:

[tex]\frac{Rate_{SO_2}}{Rate_{Xe}}=\sqrt{\frac{M_{Xe}}{M_{SO_2}}}[/tex]          .....(2)

Given values:

[tex]Rate_{Xe}=7.03\times 10^{-4}mol/hr\\M_{Xe}=131g/mol\\M_{SO_2}=64g/mol[/tex]

Plugging values in equation 2:

[tex]\frac{Rate_{SO_2}}{7.03\times 10^{-4}}=\sqrt{\frac{131}{64}}\\\\Rate_{SO_2}=7.03\times 10^{-4}\times \sqrt{\frac{131}{64}}\\\\Rate_{SO_2}=1.006\times 10^{-3}mol/hr[/tex]

Hence, the rate of effusion of [tex]SO_2[/tex] gas is [tex]1.006\times 10^{-3}mol/hr[/tex]

1.2.1. Name and explain the purpose of one law /legislation that protects citizens against cyberbullying ?​

Answers

Answer:

Federal law is a law that may protect people from digital attacks such as cyberbullying.

Explanation:

Although it is mostly based on the situation, federal law does protect those who suffer from cyberbullying. The attackers may be charged with defamation, since cyberbullying consists of spreading false information about someone on the internet, that's when the law comes in.

I WILL GIVE BRAINLIEST IF YOU ANSWER CORRECTLY


How many grams in 3.75 x 1024 atoms of F?​

Answers

Answer:

96 grams

Explanation:

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Scientists use different types of microscopes to observe objects that are not visible to the naked eye. A scientist is
reviewing various samples of pond water to determine what species of microorganisms live in the pond. The scientist
wishes to make drawings of the structure of each microorganism and study each one's method of movement. Which of
the following microscopes would be best for the scientist to use?
transmission electron microscope
b. scanning electron microscope
c. compound light microscope
d. dissecting microscope
a.
Please select the best answer from the choices provided
ОА
ОВ
D
Nox
Submit
Save and Exit
Mark this and retum
Sono

Answers

Answer:

compound light microscope

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