Nitric oxide (NO) from car exhaust is a primary air pollutant. Calculate the equilibrium constant for the reaction
N2(g) + O2(g) equilibrium reaction arrow 2 NO(g)
at 25°C using the data listed in the supporting materials.


Calculate the equilibrium constant at 1496°C, which is a typical temperature inside the cylinders of a car's engine after it has been running for some time. (Assume that both ΔrH° and ΔrS° are temperature independent.)

Answers

Answer 1

This problem is asking for the equilibrium constant at two different temperatures by describing the chemical equilibrium between gaseous nitrogen, oxygen and nitrogen monoxide at 25 °C and 1496 °C as the room temperature and the typical temperature inside the cylinders of a car's engine respectively:

N₂(g) + O₂(g) ⇄ 2 NO(g)

Thus, the calculated equilibrium constants turned out to be 6.19x10⁻³¹ and 9.87x10⁻⁵ at the aforementioned temperatures, respectively, according to the following work:

There is a relationship between the Gibbs free energy, enthalpy and entropy of the reaction, which leads to the equilibrium constant as shown below:

[tex]\Delta _rG=\Delta _rH-T\Delta _rS\\\\\Delta _rG=-RT ln(K)[/tex]

Which means we can calculate the enthalpy and entropy of reaction and subsequently the Gibbs free energy and equilibrium constant. In such a way, we calculate these two as follows, according to the enthalpies of formation and standard entropies of N₂(g), O₂(g) and NO(g) since these are assumed constant along the temperature range:

[tex]\Delta _rH=2*90.25 kJ/mol - (0 kJ/mol+0 kJ/mol)=180.5kJ/mol\\\\\Delta _rS=2*(0.211 kJ/mol*K)-(0.192kJ/mol*K+0.205kJ/mol*K)=0.025kJ/mol*K[/tex]

Then, we calculate the Gibbs free energy of reaction at both 25 °C and 1496 °C:

[tex]\Delta _rG_{25\°C}=180.5-(25+298.15)*0.025=172.42kJ/mol\\\\\Delta _rG_{1496\°C}=180.5-(1496+298.15)*0.025=135.65kJ/mol[/tex]

And finally, the equilibrium constants derived from the general Gibbs equation and Gibbs free energies of reaction:

[tex]K=exp(-\frac{\Delta _rG}{RT} )\\\\K_{25\°C}=exp[-\frac{172420 J/mol}{(8.3145\frac{J}{mol*K})(298.15K)} ]=6.19x10^{-31}\\\\K_{1496\°C}=exp[-\frac{135650J/mol}{(8.3145\frac{J}{mol*K})(1769K)} ]=9.87x10^{-5}[/tex]

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Related Questions

I need HELP ASAP PLEASE!!!!!

Answers

Answer:

All answers given in the photo

Consider a box divided in half. One side is filled with 1 mol Ne at 300. Kelvin, and the other is filled with 1 mol Rn at 300. Kelvin. A small hole is opened in the divider between the sides, allowing the gases to mix. Suppose it takes 4.0 minutes for the Rn pressure to equilibrate between the two sides. How long (min) will it take the Ne pressure to equilibrate? Enter your answer to 1 decimal place.

Answers

It will take the Ne gas approximately 1.2 s to equilibrate between the two sides.

We know that the time taken for a gas to diffuse is dependent on the molar mass of the gas. This is one of the interpretations of Graham's law of diffusion in gases. Thus, Let;

t1 = time taken for Rn to equilibrate = 4.0 s

t2 = time taken for Ne to equilibrate = ?

M1 = molar mass of Rn = 222g/mol

M2 = molar mass of Ne = 20 g/mol

Using

t1/t2 = √M1/M2

4/t2 = √222/20

4/t2 = 3.33

t2 = 4/3.33

t2 = 1.2 seconds

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PLEASE PLEASE HELP! CHEM!

Answers

Answer:

0.963158 maybe just put 0.96

Explanation:

732mmhg to atm is 0.963158 i looket it up sorry if I am wrong

what is the chemical formula of copper (ii) hyddroxide

Answers

Answer:

Cu(OH)₂

Explanation:

Hope that helps

Answer: The chemical formula is Cu(OH)₂

Heart, 5 stars, Brainiest, and 40 coins if right! Answer needed ASAP

Which statement describes what happens when Bret runs up a flight of stairs?
A. His kinetic energy is destroyed.
B. His potential energy decreases.
C. His kinetic energy is converted into potential energy.
D. His potential energy is converted into kinetic energy.

Answers

Answer:

His kinetic energy is converted into potential energy.

Explanation:

PLZ HELP ASAP! I need this done tonight please

The importance of wearing a seatbelt while riding in the car can best be explained using:

A) Newton's First Law (Law of Inertia)

B) Newton's Second Law (F=ma)

C) Newton's Third Law (Action-Reaction)

D none of the above

Answers

Explanation:

this is a chemistry question ???

anyway, it is clearly A, as seatbelts try to counteract the inertia a moving body (our bodies riding in a car) has, when the environment (the car) of this body is suddenly coming to a stop.

this inertia would otherwise try to move the body still forward resulting in a headfirst crash into and often through the windshield. which causes much more damage to the body than the bruises caused by the pressure of the seatbelts against the body counteracting the body's inertia.

but also clearly, all 3 laws play a role.

the force with which the moving body has to deal when smashing into the windshield and potentially then other objects outside the car is described by the second law.

and for any action (crash) there are corresponding reactions (like the conversion of the crash energy into some absorbing reaction : damaged soft and hard tissue in the human body, crumbled car bodies,...).

Determine the structure for a compound Z with formula C10H803.

Answers

i think it's a simple covalent structure

How many moles in 44.7 kg of carbon dioxide

Answers

Answer:

What is the number of moles of carbon present in 44 grams of carbon dioxide? One. 44 grams is a mole of carbon dioxide and there is one carbon atom in CO 2 so there is one mole of carbon. That’s how chemistry works.

Explanation:

What is the number of moles of carbon present in 44 grams of carbon dioxide? One. 44 grams is a mole of carbon dioxide and there is one carbon atom in CO 2 so there is one mole of carbon. That’s how chemistry works.

Calculate the molar mass of magnesium chloride, CaCl 2.

Ca = 40.1g, Cl = 35.5g

Answers

Answer:

Ca = 40.1 g

Cl = 35.5

So CaCl2

40.1 + 35.5×2

40.1 + 71

111.1 g

Answer above is correct

An electrolysis reaction is
A) spontaneous
B) exothermic
C) non-spontaneous
D) hydrophobic

Answers

Answer:

it's non-spontaneous

Explanation:

I hope it helps you

When Zinc-67 is bombarded with a neutron, a gamma ray is emitted. What radioactive isotope is produced?

Answers

Answer:16/29

Explanation:

The diagram shows two different methods for collecting the product of a reaction. Which setup would be better for collecting a soluble gas such as ammonia?

Answers

Answer:

The setup above is used to collect hydrogen gas

Both filtration and distillation are useful ,methods to purify or separate components of a mixture. To collect soluble gas such as ammonia the best method is distillation. Thus setup 2 is better for collection of solute.

What is distillation?

Distillation is the process of separation of compounds using  heat and condenser. The mixture is first boiled to the boiling point of solvent. When it is heated the solvent such as water passes from the beaker on which the mixture is taken.

The steam of the solvent is then cooled in the condenser tube and then liquid is collected to a second beaker. Therefore, the solute remains in the first beaker and can be collected.

Using filtration, we can only separate solution with insoluble solutes. Using filter paper the solid from the solution can be separated out.

First set up shows the filtration method  which is not applicable for collecting soluble gas like ammonia. Therefore, the second setup that is distillation is better to collect soluble gases.

To find more about distillation, refer the link below:

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soaps do not work well in hard waters. But they can still be effected it large quantities of soap are added to water. Explain why.​

Answers

The minerals in hard water react with soap and affect its cleaning capacity. It's still possible to use hard water when washing by using more soap. The additional soap will no longer be affected by the minerals in the water, so they can clean just as effectively, but you'll be wasting more soap this way.

Which bond is the most polar?

Answers

Answer:

A

Explanation:

reason:

H-F is most polar

because bond is polarized negative towards F which is the more electronegative atom.

No matter what container it is in, a liquid usually:
A.has the same volume
B.has a different volume
C.has the same shape
D.has a different color

Answers

Answer:

A

Explanation:

A liquid will will have the same color, it will not have the same shape and its volume will always be constant because you are not creating mass.

Hope this helps!

-- --- .-. ... . / -.-. --- -.. . / .. ... -. .----. - / - .... .- - / ..-. ..- -. / .- -. -.. / .. .----. -- / ..- ... .. -. --. / .- / - .-. .- -. ... .-.. .- - --- .-. / - --- --- / ... --- what did I say in Morse code? ​

Answers

Answer:

MORSE CODE ISN'T THAT FUN AND I'M USING A TRANSLATOR TOO SO

Explanation:

That is what is says in morse code.

Answer:

MORSE CODE ISN'T THAT FUN AND I'M USING A TRANSLATOR TOO SO

Explanation:

Who did the ram caught in the thicket (Genesis 22:13) represent?

Answers

Answer:

“Rams Caught in a Thicket” as an allusion to the biblical story of Abraham. They more likely represent goats, which could often be seen standing on their hind legs, to reach leaves in the trees, as seen here.

Tyra designed an experiment to demonstrate an annular solar eclipse. The steps of the
experiment are listed below.
.
e
.
Place a light bulb on a stand.
Stick a pencil into a small styrofoam ball.
Switch on the light bulb and darken the room.
Stand facing the light bulb.
Hold the pencil with styrofoam ball very close to the eye.
Observe the light bulb without moving the eye and styrofoam ball.
Tyra's experiment has a flaw. Which of these statements best describes a method to
correct the flaw in Tyra's experiment? (3 points)
.
.
Place the light bulb behind the observer.
O Clamp the styrofoam ball behind the light bulb.
O Move eye towards the right to observe the light bulb.
Hold the styrofoam ball at arm's length from the eye.

Answers

Answer:

The answer is D.

Explanation:

Hold the styrofoam ball at arm's length from the eye.

How many valence electrons does the following isotope have?

Answers

Answer:

I have solution to your question

Nitrogen is 7th element in periodic table. It contains 7 electrons in which are 2 are inner electrons and 5 are outer electrons. Here N is in -3 oxidation state. Thus, it is having 8 valence electrons.

What is an isotopes?

Isotopes of are atoms with same atomic number and different mass numbers. Almost every elements have isotopes but some of them are unstable in nature.

Atoms forms ions when they lose or gain electrons. Wen they lose electrons, they form positive ions called cations. When they gain electrons they form negative ions or anions.

Nitrogen is 7th element in periodic table. It has 7 electrons out which 2 are inner electrons and 5 are valence electrons. N needs 3 more electrons to attain octet. Thus it gains 3 electrons and forms its 3 - oxidation state.

Thus N in -3 oxidation state have 8 valence electrons.

To find more on nitrogen, refer here:

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According to Hebrews 11, what did Abraham believe God would do if Isaac was slain as a sacrifice? Please help me I need it for tonight!

Answers

Answer:

ABRAHAM DIDN’T THINK ISAAC WOULD DIE!

When they reached the mountain, Abraham told his servant, “Stay here with the donkey; I and the boy will go over there and worship and come again to you” . The text is careful to include both Abraham and Isaac in the return journey.

Or consider Isaac’s question about where the lamb for the sacrifice would come from. Abraham responds, “God himself will provide the lamb”. It seems Abraham prepared himself to do what God asked, but he expected something else to happen.

The author of the book of Hebrews gives us insight to Abraham’s thoughts. It says, “He considered that God was able even to raise [Isaac] from the dead” Instead of a resurrection, Abraham was spared the sacrifice.

Q5. A 1.35 m solution of NaCl in water is prepared. What is the mole fraction of
the NaOCI? 0.0237

Answers

Answer:

A solution contains 0.100 mol of NaCl dissolved in 8.60 mol of water.

How do many types of cells, like bacteria, reproduce?

Answers

Answer:

cells like bacteria are bisexual so they split and their offspring is 100 percent like the parent and this process happens over and over

Explanation:

I don’t wanna fail if you know the answer pls help me :(

Answers

Answer:

liquid and gas........................

In times of hot, dry, weather, some cities ban the use of garden sprinklers. Why is there such a rule

Answers

Answer:

These weather conditions are consistent with droughts, often characterized by hot, dry, weather. When this is the case, it is important to conserve water and use it only for necessities. Garden sprinklers are not essential, so their use can be sacrificed in order to provide more crucial services, such as drinking water. This rule has been put in place in order to avoid water shortages and energy crises, events that would be even more damaging during an emergency.

You have 58 g of calcium chloride (CaCl2) and you need to make a 5 M solution. You know that the molecular weight of Ca is 40 and that the molecular weight of Cl is 35.5. How many liters (L) of water would you need

Answers

Answer:

0.1045 L (4 s.f.)

Explanation:

The molecular weight, [tex]M_{r}[/tex], of calcium chloride is

[tex]M_{r}(\mathrm{CaCl_{2}}) \ = \ A_{r}(\mathrm{Ca}) \ + \ 2 \times A_{r}(\mathrm{Cl}) \ = \ (40 \ + \ 2 \times 35.5) \ \mathrm{g \ mol^{-1}} \ = \ 111 \ \mathrm{g \ mol^{-1}}[/tex], where [tex]A_{r}[/tex] is the atomic weight of the respective elements.

To calculate the number of moles (n) of calcium chloride present in 58g,

[tex]n_{\mathrm{CaCl_{2}}} \ = \ mass \ \div \ molecular \ weight \ (M_{r}) \\ \\ \-\hspace{1.13cm} = \ 58g \ \div \ 111 \ \mathrm{g \ mol^{-1}} \\ \\ \-\hspace{1.13cm} = \ 0.5225 \ \mathrm{mol \ of \ CaCl_{2}}[/tex]

Since molarity, M, is defined as the number of moles (n) of the solute per liters of a solution (L), hence to get the volume (V) required to make up a 5 molar solution is

[tex]n \ = \ M \times V \\ \\ V \-\hspace{0.05cm} = \ \displaystyle\frac{n}{M} \\ \\ V \-\hspace{0.05cm} = \displaystyle \frac{0.5225 \ \mathrm{mol}}{5 \ \mathrm{mol \ L^{-1}}} \\ \\ V \-\hspace{0.05cm} = \ 0.1045 \ \mathrm{L}[/tex]

17.42 mL of 0.1M NaOH was needed to reach the endpoint in the titration. How many moles of NaOH are in 17.42 mL of 0.1M NaOH

Answers

Answer:

0.001742moles

Explanation:

1000ml of NaOH contain 0.1moles

17.42ml of NaOH contain (0.1*17.42)/1000 moles

= 0.001742moles

1.
Light is a(n) _______wave.

Group of answer choices


A. longitudinal


B. large


C. ocean


D. transverse

Answers

Answer: D. transverse

Explanation:

Light is a transverse wave, while sound is a longitudinal wave.

By titration, it is found that 73.3 mL of 0.175 M NaOH(aq) is needed to neutralize 25.0 mL of HCl(aq). Calculate the concentration of the HCl solution.

Answers

Answer:

0.5131M

Explanation:

NaOH(aq) + HCl(aq) — NaCl(aq) + H20(l)

Mole ratio of acid to base 1:1

(Ca × Va)/ (Cb × Vb) = Na/Nb

(0.175 × 73.3)/ (Cb × 25)= 1/1

12.8275= 25 × Cb

Cb= 12.8275/25

= 0.5131M

Which species has 54 electrons

Answers

Answer: Neutral Xe atom


Explain what is meant by the term 'conservation of mass'.
Give your answer in terms of the atoms that take part in a chemical reaction

Answers

Answer:

Below

Explanation:

In a chemical reaction, per the law of conservation of mass, no atoms or subatomic particles will be created or destroyed; for example, H2O2 will decompose into H2 and O2, meaning no matter was created or destroyed.

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