Predict the major product(s) for each of the following reactions. H3O (a) 4-Chlorobut-1-ene HBr (b) 1-Chlorobut-1-ene HBr (c) 4,4-Dimethylcyclopentene H2O, H (d) Propyne 2 HCl (e) Cyclopentylethene

Answers

Answer 1

Answer:

(a) 3-bromo-1-chlorobutane

(b) 2-bromo-1-chlorobutane

(c) 3,3-dimethylcyclopentan-1-ol

(d) 1,1,2,2-tetrachloropropane

(e) 1-ethylcyclopentan-1-ol

Explanation:

We can analyze each reaction:

(a) 4-Chlorobut-1-ene + HBr

In this reaction, we have an alkene. So, we will have an addition reaction, the nucleophile "[tex]Br^-[/tex]" will be added to the most substituted carbon. In this case carbon 3 to produce 3-bromo-1-chlorobutane.

(b) 1-Chlorobut-1-ene + HBr

In this reaction, we also have an alkene. So, we will have an addition reaction, the nucleophile "[tex]Br^-[/tex]" will be added to the most substituted carbon. In this case carbon 2 to produce 2-bromo-1-chlorobutane.

(c) 4,4-Dimethylcyclopentene + H2O, H+

In this reaction, we have an alkene. So, we will have an addition reaction, the nucleophile "[tex]H_2O[/tex]" will be added to the most substituted carbon. In this case carbon 3 to produce 3,3-dimethylcyclopentan-1-ol.

(d) Propyne  + 2HCl

In this reaction, we have an alkyne. So, we will have an addition reaction, the nucleophile "[tex]Cl^-[/tex]" will be added to the most substituted carbon, but we have 2 moles of the nucleophile, so would be added 2 times and we will have as product  1,1,2,2-tetrachloropropane.

(e) Cyclopentylethene + H3O+

In this reaction, we have an alkene. So, we will have an addition reaction, the nucleophile "[tex]H_3O^+[/tex]" will be added to the most substituted carbon. But in this case, the carbon cation would be produced in carbon 1 of the ethene. So, we can have a hydride shift to produce a tertiary carbocation. With this in mind the nucleohile will be addde to this tertiary carbocation and we will have 1-ethylcyclopentan-1-ol.

See figure 1 to further explanations

Predict The Major Product(s) For Each Of The Following Reactions. H3O (a) 4-Chlorobut-1-ene HBr (b) 1-Chlorobut-1-ene

Related Questions

How many particulars are present in 2 moles of water molecules?

Answers

Answer:

4 mole hydrozen and 2 mole oxyzen

Explanation:

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and water react to form acetylene and calcium hydroxide:
CaC2(s) + 2H2O(l) → C2H2(g) + Ca(OH)2(s)ΔH = −414kJ
In the second step, acetylene, carbon dioxide and water react to form acrylic acid:
6C2H2(g) + 3CO2(g) + 4H2O(g) → 5CH2CHCO2H(g)ΔH = 132kJ
Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water, and carbon dioxide from these reactions. Round your answer to the nearest kJ.

Answers

Answer:

ΔH = -470.4kJ

Explanation:

It is possible to sum 2 or more reactions to obtain the ΔH of the reaction you want to study (Hess's law). Using the reactions:

1. CaC2(s) + 2H2O(l) → C2H2(g) + Ca(OH)2(s)ΔH = −414kJ

2. 6C2H2(g) + 3CO2(g) + 4H2O(g) → 5CH2CHCO2H(g)ΔH = 132kJ

6 times the reaction 1.

6CaC2(s) + 12H2O(l) → 6C2H2(g) + 6Ca(OH)2(s)ΔH = −414kJ*6 = -2484kJ

This reaction + 2:

6CaC2(s) + 3CO2(g) + 16H2O(l) →  + 6Ca(OH)2(s) + 5CH2CHCO2H(g) ΔH = -2484kJ + 132kJ = -2352kJ

As we want to calculate the net change enthalpy in the formation of just 1 mole of acrylic acid we need to divide this last reaction in 5:

6/5CaC2(s) + 3/5CO2(g) + 16/5H2O(l) →  + 6/5Ca(OH)2(s) + CH2CHCO2H(g) ΔH = -2352kJ / 5

ΔH = -470.4kJ

Formulate a hypothesis about the stoichiometry of the reaction between NaCl and AgNO3.

Answers

Answer:

AgCl + NaNO3 would be the products of the reaction between sodium chloride and silver nitrate.

The stoichiometry of this reaction is written below, and it is because for this reaction to be fulfilled the products have to be in equilibrium with the reactants, since the mass in the reaction is conserved and must be balanced in the amount of molecules that they react to each other.

Explanation:

NaCl + AgNO3 -------------- AgCl + NaNO3

Which of the following amino acid functional groups will influence the pKa of an amino acid residue the least if it is on an adjacent residue?A. -OH.B. -NH3.C. -CH3.D. -COOH.

Answers

Answer:

C. -CH3

Explanation:

The pKa (acid dissociation constant) of an amino acid residue is primarily influenced by the functional groups attached to the adjacent end of the amino acid chain. The acidity of a functional group depends on how electronegative the functional group is. In the given functional groups' list, the functional group with the least influence on the pKa of the amino acid is the alkyl substituent (-CH3), because they have the least electron-withdrawing capacity.

If a 250mL beaker weighs 13.473g and the same beaker plus 2.2 mL of water weighs 15.346g. How much does the 2.2 mL of water, alone, weigh? Show your work for the calculation. Be sure to use significant figures.

Answers

Given :

A 250 ml beaker weighs 13.473 g .

The same beaker plus 2.2 ml of water weighs 15.346 g.

To Find :

How much does the 2.2 ml of water, alone, weigh .

Solution :

Now, mass of water is given by :

[tex]\text{Mass of water alone = Total mass - Mass of beaker alone}\\\\Mass =15.346-13.473\ g\\\\Mass =1.873\ g[/tex]

Therefore , mass of 2.2 ml of water alone is 1.873 g .

Hence , this is the required solution .

Which of the following is a valid conversion factor:
10m/1dm
1mL/100L
100cg/1g
1cm^3/1L

Answers

C.

1 gram = 100 centigrams (centi means hundred).

Why does the lack of snow in the mountains make drought cycles worse

Answers

Answer:

lack of snow in the mountains makes drought cycles worse because mountains are a natural part of the water cycle.

Explanation:

Mountains play a critical part In the water cycle by capturing moisture in the air and it precipitates as snow and when it does this the snow will melt in the warmer seasons and flow down stream then following the rest of the water cycle if we didn't have this then the streams would run less and it would greatly disrupt the water cycle.

What are ions exactly?
Are atoms with an incomplete outer valence shell called ions?

Answers

Answer:

An ion is a charged atom or molecule. It is charged because the number of electrons do not equal the number of protons in the atom or molecule. ... When an atom is attracted to another atom because it has an unequal number of electrons and protons, the atom is called an ION.

Explanation:

What is the relationship between grams and cm³? ​

Answers

Answer:

1 gram

Explanation:

1 gram= weight of 1 cubic centimeter of pure water at temperature 4°C = 1000 milligrams = 0.001 kilogram

What is the pH of 500 mL of water after the addition of 1 mL of 2M NaOH?

Answers

Answer:

pH = 11.60

Explanation:

When we add a base, we are increasing [OH⁻], so the pH will be totally basic.

pH of water = 7

Basic pH > 7

We are adding 2 M . 1 mL = 2 mmoles

2 mmoles of OH⁻ are contained in 501 mL of total volume.

[OH⁻] = 2 mmol / 501 mL =  3.99×10⁻³ M

- log 3.99×10⁻³ M = 2.39 → pOH

pH = 14 - pOH → 11.61

Water equilibrium

2H₂O  ⇄  H₃O⁺   +  OH⁻          Kw = 1×10⁻¹⁴

NaOH  →  Na⁺   +  OH⁻

I need help with this chemistry question talking about pure substances and mixtures?

Answers

The correct answer is A. The sample is not a heterogeneous mixture

Explanation:

A heterogeneous mixture includes two or more materials and these are not completely integrated. Due to this, in most cases, if a heterogeneous mixture is filtered it is possible to separate its parts. This did not occur when Ben filtered the substance, which shows it is likely the substance is not a heterogeneous mixture. Moreover, a heterogeneous mixture does not show uniformity in terms of appearance or properties, which shows this definitely not heterogenous and Ben can safely conclude this.

what is difference between paper and absorption chromatography ​

Answers

In partition chromatography, the stationary phase is in a liquid state. ... The difference between adsorption and partition chromatography is a separation of molecules occur based on the adsorption ability in adsorption chromatography while separation occurs based on the partition in partition chromatography

which of the following tools can be used to measure mass? A.a graduated cylinder B. a triple beam balance C. a mercury thermometer D. a bathroom scale

Answers

Answer:

triple beam balance

Explanation:

The tool that can be used to measure mass is a triple beam balance. Therefore, the correct option is option B.

A graduated cylinder is used to determine a liquid's volume. A mercury thermometer is used to measure temperature. Weight is calculated on a bathroom scale and is a force rather than a mass. A typical scientific tool for calculating an object's mass is a triple beam balance.

It is composed of three beams with moveable weights that enable precise mass balancing and a pan on one end where the thing to be measured is placed. By comparing the placement of the weights on the beams to the appropriate scale, the mass of the object can be ascertained.

Therefore, the correct option is option B.

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2-methyl-2-pentene Spell out the full name of the compound.

Answers

Answer:

METHYL PENTENE or 2-METHYL PENT-2-ENE

Explanation:

The number 2 carbon carries the methyl group and the double bone is on the 2 carbon as well.

The chemical structure of the compound has been attached.

I hope this is what you were looking for.

Draw two five carbon rings that share an atom.

Answers

Here’s the steps to do this & then a photo! Hope this helps!


Draw your electron rings. The circle with the "C" is a representative nucleus, so now you'll need to indicate the electron orbitals. The number of rings you need is to tied to the number of electrons you have. Carbon has 6 electrons. Since each ring has a maximum number of electrons that can be pictured, you'll have to do some math. The first ring can have a maximum of 2 electrons, the second ring a maximum of 8, the third ring a maximum of 18, etc. Carbon has 6 electrons, so you'll need to draw two concentric rings.
Draw your electrons. You can do this a couple different ways. Some people just draw circles on the rings and fill them in. In this case, you would draw 2 on the first ring and 5 on the second ring. The best way to draw electrons is to draw them as circles with minus signs inside. This indicates not only that they are electrons, but helps remind the viewer that electrons contain a negative charge.

4. In a chemical process, you need to force a compound to bond with a halogen, causing it to lose hydrogen. Which type of reaction do
you need to perform?
A. Halogenation
B. Hydrolysis
C. Reduction
D. Ammoniation​

Answers

Answer:

Halogenation

Explanation:

Halogenation is a type of substitution reaction in which a hydrogen atom is replaced by a halogen atom in a molecule.

The molecule looses its hydrogen atom as the halogen is introduced into the molecule. This sort of reaction is very common in organic chemistry. Many hydrocarbons can be halogenated in the presence of light.

1. Isotonic saline requires a concentration of 0.85% NaCl. How much solid NaCl must be weighed out on the balance to prepare a bottle full containing 3500 ml?

Answers

Given :

Concentration of NaCl , [tex]c=0.85 \%[/tex] .

To Find :

Th amount of solid NaCl must be weighed out on the balance to prepare a bottle full containing 3500 ml .

Solution :

Concentration of NaCl is 0.85 % .

It means , 0.85 gm of NaCl in 100 ml of water .

So , amount of solid NaCl required to prepare 3500 ml solution is :

[tex]x=\dfrac{3500\times 0.85}{100}\ gm\\\\x=29.75\ gm[/tex]

Therefore , amount of solid NaCl required is 29.75 gm .

Hence , this is the required solution .

Calculate the energy change when an electron moves from n=5 to n=7. Explain/show work please.

Answers

Answer: E = 1.55 ⋅ 10 − 19 J

Explanation:  

The energy transition will be equal to  1.55 ⋅ 10 − 1 J .  

So, you know your energy levels to be n = 5 and n = 3. Rydberg's equation will allow you calculate the wavelength of the photon emitted by the electron during this transition

1 λ  = R ⋅ ( 1 n 2 final  − 1 n 2 initial  ) , where λ - the wavelength of the emitted photon; R

- Rydberg's constant -  1.0974 ⋅ 10 7 m − 1 ; n final - the final energy level - in your case equal to 3; n initial - the initial energy level - in your case equal to 5. So, you've got all you need to solve for  λ , so 1 λ  =

1.0974 ⋅10  7 m − 1 ⋅ (....     −152    

)

1

λ

=

0.07804

10

7

m

1

λ

=

1.28

10

6

m

Since  

E

=

h

c

λ

, to calculate for the energy of this transition you'll have to multiply Rydberg's equation by  

h

c

, where

h

- Planck's constant -  

6.626

10

34

J

s

c

- the speed of light -  

299,792,458 m/s

So, the transition energy for your particular transition (which is part of the Paschen Series) is  

E

=

6.626

10

34

J

s

299,792,458

m/s

1.28

10

6

m

E

=

1.55

10

19

J

Indicate the direction of polarity of each of the covalent bonds by placing the appropriate delta notation next to each end of the bond. C-O, O-CL, O-F, C-N, C-L, S-H, S-CL

Answers

Answer:

C→O, O→Cl, O→F, C→N, C←Li, S ←H, S→Cl

Explanation:

The general convention for indicating polarity in molecules is that of showing the direction of polarity from the positive to the negative part of the bond. This is indicated in the answer by arrows that show the direction of the dipole.

The negative end of the dipole must be the more electronegative element while the positive end of the dipole is the less electronegative element, hence the answer shown above.

The delta notation, indicating the polarity of for the presented covalent bonds are:

δ+   C-O   δ-δ-   O-Cl   δ+δ+   O-F   δ-δ+   C-N   δ-δ+   C-Cl   δ-δ-   S-H   δ+δ+   S-Cl   δ-

Polar bonds are those in which atoms have different electronegativities.

The delta notation is used to indicate the direction of the polarity.

The atom with the greater electronegativity acquires a partial negative charge (goes with the symbol δ-), while the atom with the lesser electronegativity acquires a partial positive charge (goes with the symbol δ+).

Let's consider the following elements with their electronegativities.

C (2.5)O (3.5)Cl (3.0)F (4.0)N (3.0)S (2.5)H (2.1)

The delta notation for the presented bonds are:

δ+   C-O   δ-δ-   O-Cl   δ+δ+   O-F   δ-δ+   C-N   δ-δ+   C-Cl   δ-δ-   S-H   δ+δ+   S-Cl   δ-

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A hybrid car holds 32 gallons of gas in its tank. If it travels from San Diego to Seattle in three tanks of gas, and gas costs $3.29 per gallon, about how much did the trip cost? Report your answer with three significant figures.

Answers

3 tanks of gas->32*3->96 gallons in total.

96*3.29->315.84

3 sig. figs. -> $315

If a dog has a mass of 21.5kg, what is his mass in the following units?
What is the dogs mass in gram?
What is the dog mass in mg?

Answers

Answer: 21.5kg in grams is 21,500 grams

21.5kg in mg is 215,000,00

Explanation:

what is neutralisation reaction?

Answers

Answer:

In chemistry, neutralization or neutralisation (see spelling differences) is a chemical reaction in which acid and a base react quantitatively with each other. In a reaction in water, neutralization results in there being no excess of hydrogen or hydroxide ions present in the solution.

Answer:

A neutralization reaction is when an acid and a base react to form water and a salt and involves the combination of H+ ions and OH- ions to generate water. The neutralization of a strong acid and strong base has a pH equal to 7

Explanation:

How many grams are in 160 pounds?

Answers

Answer:

72574.8

Explanation:

Thats what google says

Select all the correct locations on the image. In this diagram, which subatomic particles have a negative charge?

Answers

Answer:

The correct answer is: (E), Electron.

Explanation:

There are three types of subatomic particles - protons (P) have a positive charge, neutrons (N) have zero charge, and electrons (E) have a negative charge.

Hope this helps!

To see the number of atoms of an element in a given molecule we need to multiply stoichiometry to the number that is written on the foot of the element that is stoichiometry. Therefore, electron is the subatomic particles that have a negative charge.

What is atom?

Atom is the smallest particle of any element, molecule or compound. Atom can not be further divided. Atoms contains nucleus in its center and electron that revolve around the atom in fixed orbit.

In the nucleus, proton and neutron are present. Electron has -1 charge while proton has +1 charge. Neutron is neutral that is it has no charge. So overall the charge of nucleus is due to only proton, not by neutron.

Therefore, electron is the subatomic particles that have a negative charge.

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A child has a small rubber ball that is filled with water and glitter. When the ball is bounced the glitter spreads around the inside of the toy then settles back at the bottom. The mixture inside the toy would be considered which of the following?
Homogeneous


Solution


Heterogeneous


Colloid

Answers

Answer:

Heterogeneous

Explanation:

A heterogeneous mixture is a non-uniform composition in which particles of far larger size are suspended in a phase and can be easily separated from each other. In a heterogeneous mixture, the gravity pulls the suspended particles down out of solution.

The given example is a heterogeneous mixture in which glitter particles are suspended inside the toy and settles back at the bottom due to gravity. The glitter particles can also easily separated from the toy.

Hence, the correct answer is "Heterogeneous".

A chemical engineer must report the average volume of a certain pollutant produced by the plants under her supervision. Here are the data she has been given by each plant: What average volume should the chemical engineer report? Be sure your answer has the correct number of significant digits.

Answers

Answer:

[tex]V_{average}=15.34L[/tex]

Explanation:

Hello,

In this case, given the volumes of pollutants:

Macon 0.519 L

Ogiala 44.67 L

Pitt 0.826 L

The average he ought report is computed by adding them and subsequently dividing by three since there are three pollutants as shown below:

[tex]V_{average}=\frac{0.519L+44.67L+0.826L}{3} \\\\V_{average}=15.34L[/tex]

Regards.

Cobalt has the chemical symbol Co and the atomic number 27. How many protons, neutrons, and electrons would be found in an atom of cobalt-58?

Answers

Answer:

COBALT

Explanation:

CO BALT COBALT

Complete the following table for the three key subatomic particles.

Answers

Answer:

This question is incomplete without the table

Explanation:

The missing table is attached to this answer.

There are three subatomic particles found in an atom; protons, neutrons and electrons. The properties of the subatomic particles will be classified under the following subheadings (which are the empty columns/boxes in the attachment)

SYMBOL

The symbol of proton is "p⁺", the symbol of neutron is "n⁰" and the symbol of electron is "e⁻".

CHARGE

Looking at the symbol of the subatomic particles, one can guess the charge of each of the particles from the superscript.

Protons are positively charged, electrons are negatively charged while neutrons have no charge/electrically neutral.

The relative charge of proton is +1 while it's absolute charge is +1.60218 × 10⁻¹⁹

The charge of a proton was first determined by Ernest Rutherford using the gold-foil experiment

The relative charge of electron is -1 while it's absolute charge is -1.60218 × 10⁻¹⁹

The charge of an electron was first determined by R. Milikan using the oil-drop experiment

The relative charge and absolute charge of neutron is 0

The charge of a neutron was first determined by (or credited to) James Chadwick.

MASS

The relative mass (amu) of proton is 1.00727 while that of neutron is 1.00866. The relative mass (amu) of an electron is 0.00054858 while it's absolute mass (g) is 9.10939 × 10⁻²⁴.

The mass of an electron was first measured by J. J. Thomson.

The mass of a proton was first measured by (or credited to) Ernest Rutherford.

The mass of a neutron was first measured by James Chadwick.

LOCATION

The protons and neutrons are located inside the nucleus which is found in the centre of an atom while the electron(s) is/are found outside the nucleus but within the atom.

Categorize each molecule according to its hydrogen-bonding characteristics.a. CH3OCH3b. CH3CH2CH3c. CH3CH2NH2d. H2Oe. CH3OH

Answers

Answer:

H2O > CH3OH > CH3CH2NH2 > CH3OCH3 > CH3CH2CH3

Explanation:

Hydrogen bonding exists in molecules in which hydrogen is bonded to a highly electronegative element such as fluorine, chlorine, oxygen, sulphur, nitrogen etc.

Water has the highest degree of hydrogen bonding among the listed substances hence its very high boiling point, stemming from intermolecular hydrogen bonding. CH3CH2NH2 has a lesser degree of hydrogen bonding because nitrogen is less electronegative than oxygen.

Alcohols show significant hydrogen bonding in solution, the same applied to amines. However, ethers do not form hydrogen bonds with each other but they can form hydrogen bonds with other molecules such as alcohols and amines. Alkanes do not form hydrogen bonds at all.

A block of aluminum occupies a volume of 13.8 mL and weighs 43.3 g.
What is its density? Give answer with one decimal.

Answers

Answer:

3.1g/mL

Explanation:

density = mass/volume

= 43.3/ 13.8

= 3.1g/mL

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