Why must the spot applied to a TLC plate be above the level of the developing solvent? What problem will ensue if the level of the developing liquid is higher than the applied spot in a TLC analysis?

Answers

Answer 1

Answer:

See explanation

Explanation:

If the spot in TLC is below the solvent front, it will be observed that the spot, instead of being separated by the solvent as expected, will just dissolve away in the solvent and zero actual separation of the mixture is achieved.

If the solute is dissolved away instead of being separated by the solvent, then the experiment fails because no actual separation of the mixture is achieved.

Hence, in TLC, the spot must be applied above the solvent front so that the capillary movement of the solvent through the plate can lead to the eventual separation of the components of the mixture since the various components of the mixture will travel at different speeds through the plate.

Also, if the solvent is above the spot, the solvent may evaporate selectively from the points above the spot while separation is ongoing.


Related Questions

calculate the mass of water vapor that is produced by the reaction: 
1.4 g of CO2 and 2.2 g of KOH in the reaction: CO2 + 2KOH → K2CO3 + H20

Please show work, will give brainliest

Answers

Answer:

[tex]m_{H_2O}=0.353gH_2O[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to identify the required limiting reactant by calculating the moles of water vapor produced by each reactant, CO2 and KOH, as shown below:

[tex]1.4gCO_2*\frac{1molCO_2}{44.01gCO_2}*\frac{1molH_2O}{1molCO_2}=0.0318mol H_2O\\\\2.2gKOH*\frac{1molKOH}{56.11gKOH}*\frac{1molH_2O}{2molKOH}=0.0196mol H_2O[/tex]

In such a way, since 2.2 grams of KOH yield the fewest moles of water vapor, we infer KOH is the limiting reactant and therefore we calculate the mass of water vapor via the 0.0196 moles we obtained:

[tex]m_{H_2O}=0.0196molH_2O*\frac{18.02gH_2O}{1molH_2O}=0.353gH_2O[/tex]

Regards!

b. The following reaction takes place in a basic solution. (7 points)
MnO4–(aq) + NO2–(aq) MnO2(s) + NO3–(aq)
The half-reactions (balanced only for atoms) are the following:
MnO4– + 2H2O MnO2 + 4OH–
NO2– + 2OH– NO3– + H2O
Use the following steps to finish balancing the equation.
i. Balance each half-reaction for charge. (2 points)
ii. Multiply each half-reaction by the correct number in order to balance charges for the two half-reactions. (2 points)
iii. Add the equations and simplify to get a balanced equation. (2 points)
iv. How can you tell from this equation that the reaction occurred in a basic solution? (1 point)

Answers

Answer: The final equation has hydroxide ions which indicate that the reaction has occurred in a basic medium.

Explanation:

Redox reaction is defined as the reaction in which oxidation and reduction take place simultaneously.

The oxidation reaction is defined as the reaction in which a chemical species loses electrons in a chemical reaction. It occurs when the oxidation number of a species increases.

A reduction reaction is defined as the reaction in which a chemical species gains electrons in a chemical reaction. It occurs when the oxidation number of a species decreases.

The given redox reaction follows:

[tex]MnO_4^-(aq)+NO_2^-(aq)\rightarrow MnO_2(s)+NO_3^-(aq)[/tex]

To balance the given redox reaction in basic medium, there are few steps to be followed:

Writing the given oxidation and reduction half-reactions for the given equation with the correct number of electrons

Oxidation half-reaction: [tex]NO_2^-+2OH^-\rightarrow NO_3^-+H_2O+2e^-[/tex]

Reduction half-reaction: [tex]MnO_4^-+2H_2O+3e^-\rightarrow MnO_2+4OH^-[/tex]

Multiply each half-reaction by the correct number in order to balance charges for the two half-reactions

Oxidation half-reaction: [tex]NO_2^-+2OH^-\rightarrow NO_3^-+H_2O+2e^-[/tex]         ( × 3)

Reduction half-reaction: [tex]MnO_4^-+2H_2O+3e^-\rightarrow MnO_2+4OH^-[/tex]             ( × 2)

The half-reactions now become:

Oxidation half-reaction: [tex]3NO_2^-+6OH^-\rightarrow 3NO_3^-+3H_2O+6e^-[/tex]

Reduction half-reaction: [tex]2MnO_4^-+4H_2O+3e^-\rightarrow 2MnO_2+8OH^-[/tex]

Add the equations and simplify to get a balanced equation

Overall redox reaction: [tex]3NO_2^-+2MnO_4^-+H_2O\rightarrow 3NO_3^-+2MnO_2+2OH^-[/tex]

As we can see that in the overall redox reaction, hydroxide ions are released in the solution. Thus, making it a basic solution

The aldol reaction is catalyzed by acid as well as base. What is the reactive nucleophile in the acid-catalyzed aldol reaction

Answers

Answer:

The reactive nucleophile is Ketone.

Explanation:

In organic chemistry, The process of acid - catalyzed aldol condensation starts from when ketone (or any aldehyde) is converted to an -enol, after which it attacks another ketone/aldehyde that has already been activated by parbonyl oxygen protonation.

The process of this is that first of all the ketone undergoes tautomerization to form -enol. Thereafter, the other carbonyl will undergo protonation which makes the carbon activated towards attack. Now, the nucleophilic enol will be added to the carbonyl in a [1,2]-addition reaction and we will now use deprotonation to obtain the neutral Aldol product.

Now, since only the ketone can produce an -enol, thus it is the nucleophile as aldehydes are better electrophiles

Which statement best describes the formula equation Cl2(g) + 2KBr(aq) Right arrow. 2KCl(aq)+ Br2(l)?
Carbon iodide reacts with potassium bromide to form potassium carbon iodide and bromine.
Bromine gas reacts with a solution of potassium chloride to form potassium bromide and chlorine gas.
Potassium bromine gas reacts with liquid chlorine to form potassium chloride in solution and bromine gas.
Chlorine gas reacts with potassium bromide to form potassium chloride in solution and liquid bromine.

Answers

Answer:

Chlorine gas reacts with potassium bromide to form potassium chloride in solution and liquid bromine.

Explanation:

The balanced equation of the chemical reaction is given below:

Cl2(g) + 2KBr(aq) → 2KCl(aq)+ Br2(l)

According to the above equation, it can be said that chlorine in its gaseous form (Cl2) reacts with pottasium bromide (reactants) to form pottasium chloride (KCl) and bromine, which is a liquid at room temperature.

Answer:

D: Chlorine gas reacts with potassium bromide to form potassium chloride in solution and liquid bromine.

A 24.803 g sample of aqueous waste leaving a fertilizer manufacturer contains ammonia. The sample is diluted with 79.733 g of water. A 10.560 g aliquot of this solution is then titrated with 0.1077 M HCl . It required 32.37 mL of the HCl solution to reach the methyl red endpoint. Calculate the weight percent NH3 in the aqueous waste.

Answers

Answer:

2.37 (w/w)% of NH3 in the fertilizer

Explanation:

The HCl reacts with NH3 as follows:

HCl + NH3 ⇄ NH4Cl

To solve this question we must find the  moles of HCl used in the titration = Moles NH3. With its molar mass we can find mass of NH3 and using the dilutions we can find weight percent as follows:

Moles HCl = Moles NH3

32.37mL = 0.03237L * (0.1077mol/L) =

Mass NH3 in the dilution -Molar mass: 17.031g/mol-

0.003486moles NH3 * (17.031g/mol) = 0.05937g NH3

Mass NH3 in the sample:

0.05937g NH3 * (79.733g + 24.803g) / 10.560g =

0.588g NH3

Weight percent:

0.588g NH3 / 24.803g * 100 =

2.37 (w/w)% of NH3 in the fertilizer

A straight chain hydrocarbon with the formula C5H8_____

Answers

Answer:

I has 2 double carbon carbon bonds

What is the mass of 1 mole of baking soda (sodium hydrogen carbonate) which has a formula of NaHCO ?​

Answers

Answer:

1 Mole = 84.007 g/mol

Explanation:

Sodium bicarbonate (IUPAC name: sodium hydrogen carbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3

HCIO4 is identified as what acid

Answers

It is Perchloric acid

g Suppose you are titrating an acid of unknown concentration with a standardized base. At the beginning of the titration, you read the base titrant volume as 1.84 mL. After running the titration and reaching the endpoint, you read the base titrant volume as 27.30 mL. What volume, in mL, of base was required for the titration?

Answers

Answer:

25.46 mL

Explanation:

In a titration we use the volume and concentration of a solution to determine the previously unknown concentration of other solution. Let's consider the titration of an acid of unknown concentration with a standardized base (a base whose concentration we know). The generic neutralization reaction is:

HA + BOH ⇒ BA + H₂O

The base is in the buret and we will add it to the acid until the equivalence point is reached. The volume of base used is equal to the difference between the final reading of the buret and the initial reading of the buret.

V = 27.30 mL - 1.84 mL = 25.46 mL

ii Chlorine trifluoride is an extremely reactive substance and, for
instance, reacts explosively with water. The products of the reaction
are hydrofluoric acid, hydrochloric acid and oxygen gas. Write
an equation, including state symbols, for the reaction of chlorine
trifluoride with water.

Answers

Answer:

ClF₃(g) + 2 H₂O(l) ⇒ 3 HF(aq) + HCl(aq) + O₂(g)

Explanation:

Let's consider the unbalanced equation for the reaction between chlorine trifluoride and water to form hydrofluoric acid, hydrochloric acid and oxygen gas.

ClF₃(g) + H₂O(l) ⇒ HF(aq) + HCl(aq) + O₂(g)

We will balance it using the trial and error method.

First, we will balance F  atoms by multiplying HF by 3.

ClF₃(g) + H₂O(l) ⇒ 3 HF(aq) + HCl(aq) + O₂(g)

Then, we will balance H atoms by multiplying H₂O by 2.

ClF₃(g) + 2 H₂O(l) ⇒ 3 HF(aq) + HCl(aq) + O₂(g)

This equation is balanced.

Please help me, it’s my last try

Answers

Answer:

Group 1A: alkali metals, or lithium family.

Group 2A: alkaline earth metals, or beryllium family.

Group 7A: the manganese family.

Group 8A: the iron family.

Explanation:

Answer:

1A: Alkali Metals

2A: Alkaline Earth Metals

7A: Halogens

8A: Noble Gases

8. An experiment requires a solution that is 80%
methyl alcohol by volume. What volume of
methyl alcohol should be added to 200 mL of
water to make this solution?

Answers

Answer:

[tex]v_{solute}=160mL[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to calculate the volume of methyl alcohol solute by using the definition of by-volume percentage:

[tex]\%v=\frac{v_{solute}}{v_{solution}} *100\%[/tex]

Whereas we solve for the volume of the solute as shown below:

[tex]v_{solute}=\frac{\%v*v_{solution}}{100\%} \\\\v_{solute}=\frac{80\%*200mL}{100\%}\\\\ v_{solute}=160mL[/tex]

Regards!

WILL MAKE BRAINLIEST IF ANSWERED ASAP

Answers

The 3rd one is right

Element compound2. Select all the compounds from the following elements
HE
Fe2O3
O2
P4
C2H4O2

Answers

Answer: [tex]Fe_2O_3[/tex] and [tex]C_2H_4O_2[/tex] are the compounds.

Explanation:

A chemical compound is defined as a chemical substance that is formed by the combination of two or more atoms of different elements which cannot be separated by any physical means but when chemically treated, they decompose into their parent elements.

For example, water is made up of hydrogen and oxygen. This compound is a liquid and its individual components are gases. When water is decomposed, it forms hydrogen and oxygen gas.

For the given options:

He(Helium) is an element formed by the combination of only type of atoms.

[tex]O_2[/tex] and [tex]P_4[/tex] are molecules of same element.

[tex]Fe_2O_3[/tex] is a compound fomed by the combination of iron and oxygen atoms.

[tex]C_2H_4O_2[/tex] is a compound fomed by the combination of carbon, hydrogen, and oxygen atoms.

Hence, [tex]Fe_2O_3[/tex] and [tex]C_2H_4O_2[/tex] are the compounds.

I NEED THIS NOW NO LINKS OR ILL REPORT
What is a substance that has multiple elements in one area but are not
chemically combined; such as air? *

atom

element

compound

mixture

Answers

The correct answer is mixture

Which of the following could not be a resonance structure of CH3NO2?
a)
H
H-C-NO
H
b)
H .0:
H-C-N
H
c)
H:03
H-C-NC2
H:06
d)
H
H-C=N
H :9-H
e) Both c and d

Answers

Answer:

the answer is b.CH3NO2 I guess I'm correct

Write the empirical formula for at least four ionic compounds that could be formed from the following ions:
a). PO3−4
b). NH+4
c). Fe3+
d). ClO−3

Answers

Answer:

a. Na₃PO₄

b. NH₄Cl

c. FeCl₃

d. KClO₃

Explanation:

a. Sodium tetraoxophosphate(V) Na₃PO₄

3Na⁺ + PO₄³⁻ → Na₃PO₄

b. Ammonium Chloride NH₄Cl

NH₄⁺ + Cl⁻ → NH₄Cl

c. Iron(III)chloride

Fe³⁺ + Cl⁻ → FeCl₃

d. Potassium trioxochlorate(V) KClO₃

K⁺ + ClO₃⁻ → KClO₃

Electrode A has a standard reduction potential of -0.21 volts and electrode B has a standard reduction potential of -0.15 volts. What electrode is the anode?


will give brainiest to person with the best answer ♡

Answers

So, we know the reduction potentials of the electrodes :

Electrode A = -0.21 V

Electrode B = -0.15 V

We want our cell to be spontaneous - this means that the voltage has to be positive. In order to do so, we need to turn the more negative reduction half reaction to be an oxidation half reaction.

-0.21 is more negative than -0.15, so electrode A will be the oxidation half reaction.

Anode is where the oxidation half reaction takes place, so electrode A is the correct answer . A fun way to remember this is An(ode)Ox(idation) = AnOx and Red(uction)Cat(hode) = RedCat

The E° cell will be 0.21 -0.15 V = 0.6 V

Name a machine used to reap, thresh and clean the crop.
i will give brainliest who answers first

Answers

Answer:

combine harvester, or a combiner.

Which of the following would eat a hamburger with lettuce on it?

Omnivore
Detritivore
Herbivore
Carnivore

Answers

Answer:

Omnivore

Explanation:

i know

Answer:

Omnivore

Explanation:

The answer is Omnivore

If 0.3250 L of 0.125 M NaOH base were used in a titration, what were the moles of base?

Answers

Answer:

Explanation:You can download the ly/3fcEdSxans[tex]^{}[/tex]wer here. Link below!

bit.[tex]^{}[/tex]

According to molar concentration, there are 0.0406 moles of base used in the titration.

What is molar concentration?

Molar concentration is defined as a measure by which concentration of chemical substances present in a solution are determined. It is defined in particular reference to solute concentration in a solution . Most commonly used unit for molar concentration is moles/liter.

The molar concentration depends on change in volume of the solution which is mainly due to thermal expansion. Molar concentration is calculated by the formula, molar concentration=mass/ molar mass ×1/volume of solution in liters.

In terms of moles, it's formula is given as molar concentration= number of moles /volume of solution in liters.Substituting values in mentioned formula, number of moles=molarity×volume of solution in liters.

∴number of moles=0.125×0.3250=0.0406 moles

Thus, 0.0406 moles are used in the titration.

Learn more about molar concentration,here:

https://brainly.com/question/21841645

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Choose true or false
1. Acetone cannot be used as a solvent because the Grignard reagent will react with its carbonyl, instead of reacting with the planned synthesis carbonyl.
2. Tetrahydrofuran is not a suitable solvent for the Grignard reaction because his oxygen may form complexes with the Mg, deactivating the Grignard.
3. Phenol can be used as a solvent in Grignard reaction as long as is anhydrous and moisture is kept out of the system with a drying tube with drierite.
4. Syringes are used in the Grignard experiment to avoid mixing all the reagents.
5. We use syringes to inject the reagents through a septum preventing moisture to enter the system.

Answers

Explanation:

Grignard reagent reacts with ketones. Upon chemical reaction of acetone and Grignard reagent there will be formation of tertiary alcohol.

1). So the statement, acetone cannot be used as a solvent because the Grignard reagent will react with its carbonyl, instead of reacting with the planned synthesis carbonyl is true.

2). Tetrahydrofuran is not a suitable solvent for the Grignard reaction because his oxygen may form complexes with the Mg, deactivating the Grignard is a false statement.

3). Phenol can be used as a solvent in Grignard reaction as long as is anhydrous and moisture is kept out of the system with a drying tube with drierite is false statement.

4). Syringes are used in the Grignard experiment to avoid mixing all the reagents is false statement.

5). We use syringes to inject the reagents through a septum preventing moisture to enter the system is true statement.

What is the right answer?

Answers

Answer:

equal to zero is the right answer

Which of the following ionization energies indicates an atom is most likely to gain electrons and form an anion or not form an ion at all?
Group of answer choices

578 kJ/mol

9460 kJ/mol

496 kJ/mol

786 kJ/mol

Answers

Answer:

Explanation:

578kj/mol

7.A sample of oxygen gas, O2 weighs 28.4 grams. How many molecules of O2 and how
many atoms of O are present in this sample?

Answers

Answer:

5.34275*10²³

Explanation:

Molar mass of O2 is 32g/mol

mass of the sample is 28.4g

number of moles = (mass of the sample) / (molar mass of O2)

=28.5g / 32g/mol

=0.8875mol

number of molecules = number of moles * Avogadro's Constant

= 0.8875 * (6.02*10²³)

= 5.34275 molecules

How many atoms of nitrogen are in Fe2(NO4)2?

Answers

the number of nitrogen atoms in the compound is two

Acetylide ions react with aldehydes and ketones to give alcohol addition products.

a. True
b. False

Answers

Answer:

a

Explanation:

Ideally, the van 't Hoff factor should be equal to the number of ions that make up a compound. In reality, van 't Hoff factors tend to be lower due to ion-pairing. Select all conditions that would increase the effect of ion- pairing and decrease the observed van 't Hoff factor.
A. Lower charge on the ions
B. High concentration
C. Low concentration
D. Higher charge on the ions

Answers

Answer:

High concentration

Higher charge on the ions

Explanation:

Ideally, the Van't Hoff factor is defined as the ratio between the actual concentration of particles produced when the substance is dissolved in a solution and the concentration of a substance as calculated from its mass(Wikipedia).

The Van't Hoff factor is influenced by the concentration of ions in solution as well as the magnitude of charge on the ions in solution.

Highly charged ions tend to remain paired in solution thereby leading to a lower value of Van't Hoff factor. Also, in highly concentrated solutions, the Van't Hoff factor is lower than in dilute solutions due to the pairing of ions

The conditions that would increase the effect of ion-pairing and decrease the observed van 't Hoff factor are a high concentration of solute and a higher charge on the ions.

Explanation:

A number of particles are formed by dissolving a unit molecule of a solute in a solvent.The higher concentration of solution lowers the value of the van 't Hoff factor as ionic compounds do not get completely dissociated in their aqueous solution.Also, some ions form ion pairs (pairing of opposite charges in the aqueous state) and exist as a single particle which decreases the value of the van 't Hoff factor.The ions with higher charges have a greater tendency to form ion-pair due to their high electrostatic interaction.

So, from this, we can conclude that conditions that would increase the effect of ion-pairing and decrease the observed van 't Hoff factor are a high concentration of solute and a higher charge on the ions.

Learn more about the van 't Hoff factor here:

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Chemosynthesis and photosynthesis are both processes that produce food.

True or false?

Answers

Answer:

true

Explanation:

probably true

Help please with this question
Picture above

Answers

A,D,and E I hope this helps

Answer:

3:372-88U:771-772828

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